1. Your wife may execute a SPA or GPA in your favour. If it's only for selling the property, SPA will suffice.
2. The POA executed by your wife has to be notarized/ countersigned by the Indian Consulate in U.K. and then it has to be adjudicated in the jurisdictional District Registrar's Office in Mumbai.
3. After following the above procedure, the POA would be legally valid for you to sell the joint property to a prospective buyer in India, by acting as Attorney to your wife, on her behalf. in respect of her share in the joint property.